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DOI:

10.1002/adma.201405840

Authors:

Kensuke Takechi, Yuichi Kato, Yoko Hase

Abstract:

A redox-active supercooled liquid is obtained by forming a « solvate ionic liquid » from a mixture of a stabilized organic radical and a specific Li salt and stabilizing the mixture further below their melting points. As a catholyte, the addition of an appropriate amount of water helps to enhance the electrochemical advantage while maintaining its supercooled nature and the liquid shows a high energy density of 200 W h L(-1) with reversible charge/discharge.