{"id":460,"date":"2026-04-15T13:50:05","date_gmt":"2026-04-15T13:50:05","guid":{"rendered":"https:\/\/citations.tools.bio-logic.fr\/?p=460"},"modified":"2026-04-15T13:50:05","modified_gmt":"2026-04-15T13:50:05","slug":"under-pressure-mechanochemical-effects-on-structure-and-ion-conduction-in-the-sodium-ion-solid-electrolyte-na-3-ps-4","status":"publish","type":"post","link":"https:\/\/citations.tools.bio-logic.fr\/?p=460","title":{"rendered":"Under Pressure: Mechanochemical Effects on Structure and Ion Conduction in the Sodium-Ion Solid Electrolyte Na <sub>3<\/sub> PS <sub>4<\/sub>"},"content":{"rendered":"<h4>DOI:<\/h4>\n<p><a href=\"https:\/\/doi.org\/10.1021\/jacs.0c06668\" target=\"_blank\" rel=\"noopener\">10.1021\/jacs.0c06668<\/a><\/p>\n<h4>Authors:<\/h4>\n<p>Theodosios Famprikis, \u00d6mer Ula\u015f Kudu, James A. Dawson, Pieremanuele Canepa, Fran\u00e7ois Fauth, Emmanuelle Suard, Mohamed Zbiri, Damien Dambournet, Olaf J. Borkiewicz, H. Bouyanfif, Steffen Emge, Sorina Cre\u0163u, Jean\u2010No\u00ebl Chotard, Clare P. Grey, Wolfgang G. Zeier, M. Saiful Islam, Christian Masquelier<\/p>\n<h4>Abstract:<\/h4>\n<p>Fast-ion conductors are critical to the development of solid-state batteries. The effects of mechanochemical synthesis that lead to increased ionic conductivity in an archetypical sodium-ion conductor Na<sub>3<\/sub>PS<sub>4<\/sub> are not fully understood. We present here a comprehensive analysis based on diffraction (Bragg and pair distribution function), spectroscopy (impedance, Raman, NMR and INS), and <i>ab initio<\/i> simulations aimed at elucidating the synthesis-property relationships in Na<sub>3<\/sub>PS<sub>4<\/sub>. We consolidate previously reported interpretations regarding the local structure of ball-milled samples, underlining the sodium disorder and showing that a local tetragonal framework more accurately describes the structure than the originally proposed cubic one. Through variable-pressure impedance spectroscopy measurements, we report for the first time the activation volume for Na<sup>+<\/sup> migration in Na<sub>3<\/sub>PS<sub>4<\/sub>, which is \u223c30% higher for the ball-milled samples. Moreover, we show that the effect of ball-milling on increasing the ionic conductivity of Na<sub>3<\/sub>PS<sub>4<\/sub> to \u223c10<sup>-4<\/sup> S\/cm can be reproduced by applying external pressure on a sample from conventional high-temperature ceramic synthesis. We conclude that the key effects of mechanochemical synthesis on the properties of solid electrolytes can be analyzed and understood in terms of pressure, strain, and activation volume.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>DOI: 10.1021\/jacs.0c06668 Authors: Theodosios Famprikis, \u00d6mer Ula\u015f Kudu, James A. Dawson, Pieremanuele Canepa, Fran\u00e7ois Fauth, Emmanuelle Suard, Mohamed Zbiri, Damien Dambournet, Olaf J. Borkiewicz, H. Bouyanfif, Steffen Emge, Sorina Cre\u0163u, Jean\u2010No\u00ebl Chotard, Clare P. Grey, Wolfgang G. Zeier, M. Saiful Islam, Christian Masquelier Abstract: Fast-ion conductors are critical to the development of solid-state batteries. The [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[4],"tags":[],"class_list":["post-460","post","type-post","status-publish","format-standard","hentry","category-cesh"],"_links":{"self":[{"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/posts\/460","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=460"}],"version-history":[{"count":0,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/posts\/460\/revisions"}],"wp:attachment":[{"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=460"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=460"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=460"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}