{"id":200,"date":"2026-04-16T06:10:36","date_gmt":"2026-04-16T06:10:36","guid":{"rendered":"https:\/\/citations.tools.bio-logic.fr\/?p=200"},"modified":"2026-04-16T06:10:36","modified_gmt":"2026-04-16T06:10:36","slug":"an-unprecedented-ni14siw9-hybrid-polyoxometalate-with-high-photocatalytic-hydrogen-evolution-activity","status":"publish","type":"post","link":"https:\/\/citations.tools.bio-logic.fr\/?p=200","title":{"rendered":"An unprecedented {Ni<sub>14<\/sub>SiW<sub>9<\/sub>} hybrid polyoxometalate with high photocatalytic hydrogen evolution activity"},"content":{"rendered":"<h4>DOI:<\/h4>\n<p><a href=\"https:\/\/doi.org\/10.1039\/c9cc01269a\" target=\"_blank\" rel=\"noopener\">10.1039\/c9cc01269a<\/a><\/p>\n<h4>Authors:<\/h4>\n<p>Gr\u00e9goire Paille, Amandine Boulmier, Alexandre Bensa\u00efd, Minh\u2010Huong Ha\u2010Thi, Mai T.T. Tran, Thomas Pino, J\u00e9r\u00f4me Marrot, \u00c9ric Rivi\u00e8re, Christopher H. Hendon, Olivier Oms, Mar\u00eda G\u00f3mez-Mingot, Marc Fontecave, Caroline Mellot\u2010Draznieks, Anne Dolbecq, Pierre Mialane<\/p>\n<h4>Abstract:<\/h4>\n<p>A unique polyoxometalate complex made up of a tetradecanuclear nickel bisphosphonate cluster capping a {SiW9} unit has been characterized. This stable compound exhibits a high hydrogen evolution reaction photocatalytic activity under visible light irradiation via a reductive quenching mechanism.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>DOI: 10.1039\/c9cc01269a Authors: Gr\u00e9goire Paille, Amandine Boulmier, Alexandre Bensa\u00efd, Minh\u2010Huong Ha\u2010Thi, Mai T.T. Tran, Thomas Pino, J\u00e9r\u00f4me Marrot, \u00c9ric Rivi\u00e8re, Christopher H. Hendon, Olivier Oms, Mar\u00eda G\u00f3mez-Mingot, Marc Fontecave, Caroline Mellot\u2010Draznieks, Anne Dolbecq, Pierre Mialane Abstract: A unique polyoxometalate complex made up of a tetradecanuclear nickel bisphosphonate cluster capping a {SiW9} unit has been characterized. [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[27],"tags":[],"class_list":["post-200","post","type-post","status-publish","format-standard","hentry","category-sp-300-potentiostat"],"_links":{"self":[{"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/posts\/200","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=200"}],"version-history":[{"count":0,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/posts\/200\/revisions"}],"wp:attachment":[{"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=200"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=200"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=200"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}