{"id":1616,"date":"2025-12-23T10:36:13","date_gmt":"2025-12-23T10:36:13","guid":{"rendered":"https:\/\/citations.tools.bio-logic.fr\/?p=1616"},"modified":"2025-12-23T10:36:13","modified_gmt":"2025-12-23T10:36:13","slug":"resolving-the-role-of-configurational-entropy-in-improving-cycling-performance-of-multicomponent-hexacyanoferrate-cathodes-for-sodium%e2%80%90ion-batteries","status":"publish","type":"post","link":"https:\/\/citations.tools.bio-logic.fr\/?p=1616","title":{"rendered":"Resolving the Role of Configurational Entropy in Improving Cycling Performance of Multicomponent Hexacyanoferrate Cathodes for Sodium\u2010Ion Batteries"},"content":{"rendered":"<h4>DOI:<\/h4>\n<p><a href=\"https:\/\/doi.org\/10.1002\/adfm.202202372\" target=\"_blank\" rel=\"noopener\">10.1002\/adfm.202202372<\/a><\/p>\n<h4>Authors:<\/h4>\n<p>Yanjiao Ma, Yang Hu, Yohanes Pramudya, Thomas Diemant, Qingsong Wang, Damian Goonetilleke, Yushu Tang, Bei Zhou, Horst Hahn, Wolfgang Wenzel, Maximilian Fichtner, Yuan Ma, Ben Breitung, Torsten Brezesinski<\/p>\n<h4>Abstract:<\/h4>\n<p>Abstract Mn\u2010based hexacyanoferrate (Mn\u2010HCF) cathodes for Na\u2010ion batteries usually suffer from poor reversibility and capacity decay resulting from unfavorable phase transitions and structural degradation during cycling. To address this issue, the high\u2010entropy concept is here applied to Mn\u2010HCF materials, significantly improving the sodium storage capabilities of this system via a solid\u2010solution mechanism with minor crystallographic changes upon de\u2010\/sodiation. Complementary structural, electrochemical, and computational characterization methods are used to compare the behavior of high\u2010, medium\u2010, and low\u2010entropy multicomponent Mn\u2010HCFs resolving, to our knowledge for the first time, the link between configurational entropy\/compositional disorder (entropy\u2010mediated suppression of phase transitions, etc.) and cycling performance\/stability in this promising class of next\u2010generation cathode materials.<\/p>\n","protected":false},"excerpt":{"rendered":"<h4>DOI:<\/h4>\n<div class=\"b-doi\">10.1002\/adfm.202202372<\/div>\n<h4>Authors:<\/h4>\n<div class=\"b-author\">Yanjiao Ma, Yang Hu, Yohanes Pramudya, Thomas Diemant, Qingsong Wang, Damian Goonetilleke, Yushu Tang, Bei Zhou, Horst Hahn, Wolfgang Wenzel, Maximilian Fichtner, Yuan Ma, Ben Breitung, Torsten Brezesinski<\/div>\n<h4>Abstract:<\/h4>\n<div class=\"b-intro\">Abstract Mn\u2010based hexacyanoferrate (Mn\u2010HCF) cathodes for Na\u2010ion batteries usually suffer from poor reversibility and capacity decay resulting from unfavorable phase transitions and structural degradation during cycling. To address this issue, the high\u2010entropy concept is here applied to Mn\u2010HCF materials, significantly improving the sodium storage capabilities of this system via a&hellip;<\/div>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[25],"tags":[],"class_list":["post-1616","post","type-post","status-publish","format-standard","hentry","category-sp-150-potentiostat"],"_links":{"self":[{"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/posts\/1616","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=1616"}],"version-history":[{"count":0,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/posts\/1616\/revisions"}],"wp:attachment":[{"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=1616"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=1616"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=1616"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}