{"id":1548,"date":"2025-12-23T10:37:08","date_gmt":"2025-12-23T10:37:08","guid":{"rendered":"https:\/\/citations.tools.bio-logic.fr\/?p=1548"},"modified":"2025-12-23T10:37:08","modified_gmt":"2025-12-23T10:37:08","slug":"emulsion-polymerizations-for-a-sustainable-preparation-of-efficient-tempo%e2%80%90based-electrodes","status":"publish","type":"post","link":"https:\/\/citations.tools.bio-logic.fr\/?p=1548","title":{"rendered":"Emulsion Polymerizations for a Sustainable Preparation of Efficient TEMPO\u2010based Electrodes"},"content":{"rendered":"<h4>DOI:<\/h4>\n<p><a href=\"https:\/\/doi.org\/10.1002\/cssc.202002251\" target=\"_blank\" rel=\"noopener\">10.1002\/cssc.202002251<\/a><\/p>\n<h4>Authors:<\/h4>\n<p>Simon Muench, P. Gerlach, Ren\u00e9 Burges, Maria Strumpf, Stephanie Hoeppener, Andreas Wild, Alexandra Lex, Andrea Balducci, Johannes C. Brendel, Ulrich S. Schubert<\/p>\n<h4>Abstract:<\/h4>\n<p>Abstract Organic polymer\u2010based batteries represent a promising alternative to present\u2010day metal\u2010based systems and a valuable step toward printable and customizable energy storage devices. However, most scientific work is focussed on the development of new redox\u2010active organic materials, while straightforward manufacturing and sustainable materials and production will be a necessary key for the transformation to mass market applications. Here, a new synthetic approach for 2,2,6,6\u2010tetramethyl\u20104\u2010piperinidyl\u2010 N \u2010oxyl (TEMPO)\u2010based polymer particles by emulsion polymerization and their electrochemical investigation are reported. The developed emulsion polymerization protocol based on an aqueous reaction medium allowed the sustainable synthesis of a redox\u2010active electrode material, combined with simple variation of the polymer particle size, which enabled the preparation of nanoparticles from 35 to 138 nm. Their application in cell experiments revealed a significant effect of the size of the active\u2010polymer particles on the performance of poly(2,2,6,6\u2010tetramethyl\u20104\u2010piperinidyl\u2010 N \u2010oxyl methacrylate) (PTMA)\u2010based electrodes. In particular rate capabilities were found to be reduced with larger diameters. Nevertheless, all cells based on the different particles revealed the ability to recover from temporary capacity loss due to application of very high charge\/discharge rates.<\/p>\n","protected":false},"excerpt":{"rendered":"<h4>DOI:<\/h4>\n<div class=\"b-doi\">10.1002\/cssc.202002251<\/div>\n<h4>Authors:<\/h4>\n<div class=\"b-author\">Simon Muench, P. Gerlach, Ren\u00e9 Burges, Maria Strumpf, Stephanie Hoeppener, Andreas Wild, Alexandra Lex, Andrea Balducci, Johannes C. Brendel, Ulrich S. Schubert<\/div>\n<h4>Abstract:<\/h4>\n<div class=\"b-intro\">Abstract Organic polymer\u2010based batteries represent a promising alternative to present\u2010day metal\u2010based systems and a valuable step toward printable and customizable energy storage devices. However, most scientific work is focussed on the development of new redox\u2010active organic materials, while straightforward manufacturing and sustainable materials and production will be a necessary key&hellip;<\/div>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[25],"tags":[],"class_list":["post-1548","post","type-post","status-publish","format-standard","hentry","category-sp-150-potentiostat"],"_links":{"self":[{"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/posts\/1548","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=1548"}],"version-history":[{"count":0,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/posts\/1548\/revisions"}],"wp:attachment":[{"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=1548"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=1548"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=1548"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}