{"id":1536,"date":"2025-12-23T10:37:08","date_gmt":"2025-12-23T10:37:08","guid":{"rendered":"https:\/\/citations.tools.bio-logic.fr\/?p=1536"},"modified":"2025-12-23T10:37:08","modified_gmt":"2025-12-23T10:37:08","slug":"direct-and-indirect-electrooxidation-of-glycerol-to-value%e2%80%90added-products","status":"publish","type":"post","link":"https:\/\/citations.tools.bio-logic.fr\/?p=1536","title":{"rendered":"Direct and Indirect Electrooxidation of Glycerol to Value\u2010Added Products"},"content":{"rendered":"<h4>DOI:<\/h4>\n<p><a href=\"https:\/\/doi.org\/10.1002\/cssc.202100556\" target=\"_blank\" rel=\"noopener\">10.1002\/cssc.202100556<\/a><\/p>\n<h4>Authors:<\/h4>\n<p>Michael Guschakowski, Uwe Schr\u00f6der<\/p>\n<h4>Abstract:<\/h4>\n<p>Abstract In this work, different approaches for the direct and indirect electrooxidation of glycerol, a by\u2010product of oleochemistry and biodiesel production, for the synthesis of value\u2010added products and of intermediates for biofuel\/electrofuel production, were investigated and compared. For the direct electrooxidation, metallic catalysts were used, whose surfaces were modified by promoters or second catalysts. Bi\u2010modified Pt electrodes (Pt x Bi y \/C) served as model systems for promoter\u2010supported electrocatalysis, whereas IrO 2 \u2010modified RuO 2 electrodes were studied as catalyst combinations, which were compared under acidic conditions with the respective monometallic catalysts (Pt\/C, RuO 2 \/Ti, IrO 2 \/Ti). Furthermore, inorganic halide mediators (chloride, bromide, iodide) and organic nitroxyl mediators (4\u2010oxo\u20102,2,6,6\u2010tetramethyl\u2010piperidin\u20101\u2010oxyl and 4\u2010acetamido\u20102,2,6,6\u2010tetramethyl\u2010piperidin\u20101\u2010oxyl) were evaluated for indirect electrooxidation. These different approaches were discussed regarding selectivity, conversion, and coulombic efficiency of the electrochemical glycerol oxidation.<\/p>\n","protected":false},"excerpt":{"rendered":"<h4>DOI:<\/h4>\n<div class=\"b-doi\">10.1002\/cssc.202100556<\/div>\n<h4>Authors:<\/h4>\n<div class=\"b-author\">Michael Guschakowski, Uwe Schr\u00f6der<\/div>\n<h4>Abstract:<\/h4>\n<div class=\"b-intro\">Abstract In this work, different approaches for the direct and indirect electrooxidation of glycerol, a by\u2010product of oleochemistry and biodiesel production, for the synthesis of value\u2010added products and of intermediates for biofuel\/electrofuel production, were investigated and compared. For the direct electrooxidation, metallic catalysts were used, whose surfaces were modified by&hellip;<\/div>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[25],"tags":[],"class_list":["post-1536","post","type-post","status-publish","format-standard","hentry","category-sp-150-potentiostat"],"_links":{"self":[{"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/posts\/1536","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=1536"}],"version-history":[{"count":0,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/posts\/1536\/revisions"}],"wp:attachment":[{"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=1536"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=1536"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=1536"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}