{"id":1144,"date":"2026-04-15T12:41:32","date_gmt":"2026-04-15T12:41:32","guid":{"rendered":"https:\/\/citations.tools.bio-logic.fr\/?p=1144"},"modified":"2026-04-15T12:41:32","modified_gmt":"2026-04-15T12:41:32","slug":"a-consideration-of-the-application-of-koutecky-levich-plots-in-the-diagnoses-of-charge-transfer-mechanisms-at-rotated-disk-electrodes","status":"publish","type":"post","link":"https:\/\/citations.tools.bio-logic.fr\/?p=1144","title":{"rendered":"A Consideration of the Application of Kouteck\u00fd-Levich Plots in the Diagnoses of Charge-Transfer Mechanisms at Rotated Disk Electrodes"},"content":{"rendered":"<h4>DOI:<\/h4>\n<p><a href=\"https:\/\/doi.org\/10.1002\/1521-4109(200202)14:3165::aid-elan1653.0.co;2-6\" target=\"_blank\" rel=\"noopener\">10.1002\/1521-4109(200202)14:3&lt;165::aid-elan165&gt;3.0.co;2-6<\/a><\/p>\n<h4>Authors:<\/h4>\n<p>Stephen E. Treimer, Andrew P.-C. Tang, Dennis C. Johnson<\/p>\n<h4>Abstract:<\/h4>\n<p>It has become common practice to estimate the numbers of electrons (n, eq mol\u22121) transferred in faradaic reactions at rotated disk electrodes (RDEs) from the slope of plots of reciprocal current (1\/I) vs. reciprocal square root of rotational velocity (1\/\u03c91\/2). This practice is based on the Kouteck\u00fd-Levich equation derived for a one-step electron-transfer mechanism. Furthermore, the intercept of the Kouteck\u00fd-Levich plot is assumed to be a reciprocal function of the heterogeneous rate constant (kh, cm s\u22121) for the electron-transfer process. In this review, we examine the validity of the practice of estimating values of n and kh for various multi-step mechanisms at RDEs.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>DOI: 10.1002\/1521-4109(200202)14:3&lt;165::aid-elan165&gt;3.0.co;2-6 Authors: Stephen E. Treimer, Andrew P.-C. Tang, Dennis C. Johnson Abstract: It has become common practice to estimate the numbers of electrons (n, eq mol\u22121) transferred in faradaic reactions at rotated disk electrodes (RDEs) from the slope of plots of reciprocal current (1\/I) vs. reciprocal square root of rotational velocity (1\/\u03c91\/2). This practice [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[3],"tags":[],"class_list":["post-1144","post","type-post","status-publish","format-standard","hentry","category-blurev-rde-rrde"],"_links":{"self":[{"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/posts\/1144","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=1144"}],"version-history":[{"count":0,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=\/wp\/v2\/posts\/1144\/revisions"}],"wp:attachment":[{"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=1144"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=1144"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/citations.tools.bio-logic.fr\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=1144"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}